Functional group: Difference between revisions

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imported>Infinitehoax
m Groups containing sulfur: Added hyperlinks
 
imported>Д.Ильин
img
 
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| [[File:Alkene-2D-skeletal.svg|75px|Alkene]]
| [[File:Alkene-2D-skeletal.svg|75px|Alkene]]
| alkenyl- || -ene
| alkenyl- || -ene
| [[File:Ethylene.svg|75px|ethylene]]<br>[[Ethylene]]<br>''(Ethene)''
| [[File:Ethenv2.svg|75px|ethylene]]<br>[[Ethylene]]<br>''(Ethene)''
|-
|-
| [[Alkyne]] || [[Alkyne|Alkynyl]]
| [[Alkyne]] || [[Alkyne|Alkynyl]]
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| alkynyl- || -yne
| alkynyl- || -yne
| <chem>H-C#C-H</chem><br>[[Acetylene]]<br>''(Ethyne)''
| <chem>H-C#C-H</chem><br>[[Acetylene]]<br>''(Ethyne)''
|-
|-
|-
| [[Benzene|Benzene derivative]]
| [[Benzene|Benzene derivative]]
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| RC<sub>6</sub>H<sub>5</sub><br>RPh
| RC<sub>6</sub>H<sub>5</sub><br>RPh
| [[File:Phenyl-group.svg|75px|Phenyl]]
| [[File:Phenyl-group.svg|75px|Phenyl]]
| phenyl- || -benzene
| phenyl- || &#8209;benzene
| [[File:Cumene-skeletal.svg|75px]]<br>[[Cumene]]<br>''(Isopropylbenzene)''
| [[File:Cumene-skeletal.svg|75px]]<br>[[Cumene]]<br>''(Isopropylbenzene)''
|-
|}
|}
There are also a large number of branched or ring alkanes that have specific names, e.g., [[tert-butyl]], [[bornyl]], [[cyclohexyl]], etc. There are several functional groups that contain an alkene such as [[vinyl group]], [[allyl group]], or [[Acryl|acrylic group]]. Hydrocarbons may form charged structures: positively charged [[carbocation]]s or negative [[carbanion]]s. Carbocations are often named ''-um''. Examples are [[tropylium]] and [[triphenylmethyl]] cations and the [[cyclopentadienyl]] anion.
There are also a large number of branched or ring alkanes that have specific names, e.g., [[tert-butyl]], [[bornyl]], [[cyclohexyl]], etc. There are several functional groups that contain an alkene such as [[vinyl group]], [[allyl group]], or [[Acryl|acrylic group]]. Hydrocarbons may form charged structures: positively charged [[carbocation]]s or negative [[carbanion]]s. Carbocations are often named ''-um''. Examples are [[tropylium]] and [[triphenylmethyl]] cations and the [[cyclopentadienyl]] anion.
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===Groups containing oxygen===
===Groups containing oxygen===
Compounds that contain C–O bonds each possess differing reactivity based upon the location and [[orbital hybridisation|hybridization]] of the C–O bond, owing to the electron-withdrawing effect of sp-hybridized oxygen (carbonyl groups) and the donating effects of sp<sup>2</sup>-hybridized oxygen (alcohol groups).
Compounds that contain C–O bonds each possess differing reactivity based upon the location and [[orbital hybridisation|hybridization]] of the C–O bond, owing to the electron-withdrawing effect of sp²-hybridized oxygen (carbonyl groups) and the donating effects of sp³-hybridized oxygen (alcohol groups).
{| class="wikitable" style="background: #ffffff; text-align: center;width:300px"
{| class="wikitable" style="background: #ffffff; text-align: center;width:300px"
|-
|-
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|-
|-
| [[Alcohol (chemistry)|Alcohol]]
| [[Alcohol (chemistry)|Alcohol]]
  || [[Hydroxy]]
  || [[Hydroxyl|Hydroxy]]
| ROH
| ROH
| [[File:Hydroxy-group-bw.svg|60px|center|Hydroxyl]]
| [[File:Hydroxy-group-bw.svg|60px|center|Hydroxyl]]
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| RCOX
| RCOX
| [[File:Acyl-halide-skeletal2D.svg|75px|Acyl halide]]
| [[File:Acyl-halide-skeletal2D.svg|75px|Acyl halide]]
| carbonofluoridoyl-<br>carbonochloridoyl-<br>carbonobromidoyl-<br>carbonoiodidoyl- || -oyl '''fluoride'''<br> -oyl '''chloride'''<br> -oyl '''bromide'''<br> -oyl '''iodide'''
| carbonofluoridoyl-<br>carbonochloridoyl-<br>carbonobromidoyl-<br>carbonoiodidoyl- || -oyl '''halide'''
| [[File:Acetyl-chloride.svg|75px|Acetyl chloride]]<br>[[Acetyl chloride]]<br>''(Ethanoyl chloride)''
| [[File:Acetyl-chloride.svg|75px|Acetyl chloride]]<br>[[Acetyl chloride]]<br>''(Ethanoyl chloride)''
|-
|-
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| alkanoyloxy-<br>or<br>alkoxycarbonyl
| alkanoyloxy-<br>or<br>alkoxycarbonyl
| alkyl alkan'''oate'''
| alkyl alkan'''oate'''
| [[File:Ethyl butyrate.png|75px|Ethyl butyrate]]<br>[[Ethyl butyrate]]<br>''(Ethyl butanoate)''
| [[File:Ethylbutyrat.svg|75px|Ethyl butyrate]]<br>[[Ethyl butyrate]]<br>''(Ethyl butanoate)''
|-
|-
| [[Organic peroxide|Hydroperoxide]]
| [[Organic peroxide|Hydroperoxide]]
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| [[Hemiketal]] || [[Hemiketal]]
| [[Hemiketal]] || [[Hemiketal]]
| RC(ORʺ)(OH)R′
| RC(ORʺ)(OH)R′
| [[File:Hemiketal-2D-skeletal.png|75px|Hemiketal]]
| [[File:Hemiketal-2D-skeletal.svg|75px|Hemiketal]]
| alkoxy -ol
| alkoxy -ol
| -one alkyl '''hemiketal'''
| -one alkyl '''hemiketal'''
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| [[File:1°-amino-group.png|75px|Primary amine]]
| [[File:1°-amino-group.png|75px|Primary amine]]
| amino- || -amine
| amino- || -amine
| [[File:Methylamine-2D.png|75px|methylamine]]<br>[[Methylamine]]<br>''(Methanamine)''
| [[File:Methylamine-2D.svg|75px|methylamine]]<br>[[Methylamine]]<br>''(Methanamine)''
|-
|-
| [[amine|Secondary amine]]
| [[amine|Secondary amine]]
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|-
|-
| [[imine|Secondary ketimine]]
| [[imine|Secondary ketimine]]
| RC(=NR'')R'
| RC(=NR")R'
| [[File:Imine-(secondary)-skeletal.svg|75px|Imine]]
| [[File:Imine-(secondary)-skeletal.svg|75px|Imine]]
| imino- || -imine
| imino- || -imine
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| cyano-
| cyano-
| alkane'''nitrile'''<br>alkyl '''cyanide'''
| alkane'''nitrile'''<br>alkyl '''cyanide'''
| [[File:Benzonitrile structure.png|75px|Benzonitrile]]<br>[[Benzonitrile]]<br>''(Phenyl cyanide)''
| [[File:Benzonitrile.svg|75px|Benzonitrile]]<br>[[Benzonitrile]]<br>''(Phenyl cyanide)''
|-
|-
| [[Isonitrile]] || RNC
| [[Isonitrile]] || RNC
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| -thioyl-<br>(-CSR')<br>or<br>sulfanylidene-<br>(=S)
| -thioyl-<br>(-CSR')<br>or<br>sulfanylidene-<br>(=S)
| -'''thione'''
| -'''thione'''
| [[File:Thiobenzophenone-2D-skeletal.png|75px|Diphenylmethanethione]]<br>[[Diphenylmethanethione]]<br>([[Thiobenzophenone]])
| [[File:Thiobenzophenone.svg|75px|Diphenylmethanethione]]<br>[[Diphenylmethanethione]]<br>([[Thiobenzophenone]])
|-
|-
| [[Thial]]
| [[Thial]]
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| methanethioyl-<br>(-CSH)<br>or<br>sulfanylidene-<br>(=S)
| methanethioyl-<br>(-CSH)<br>or<br>sulfanylidene-<br>(=S)
| -'''thial'''
| -'''thial'''
|
|[[File:Thioformaldehyde-2D.png|frameless|70x70px]]
[[Thioformaldehyde]]
(methanethial)
|-
|-
|rowspan=2| [[Thiocarboxylic acid]]
|rowspan=2| [[Thiocarboxylic acid]]