Functional group: Difference between revisions
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imported>Infinitehoax m →Groups containing sulfur: Added hyperlinks |
imported>Д.Ильин img |
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| [[File:Alkene-2D-skeletal.svg|75px|Alkene]] | | [[File:Alkene-2D-skeletal.svg|75px|Alkene]] | ||
| alkenyl- || -ene | | alkenyl- || -ene | ||
| [[File: | | [[File:Ethenv2.svg|75px|ethylene]]<br>[[Ethylene]]<br>''(Ethene)'' | ||
|- | |- | ||
| [[Alkyne]] || [[Alkyne|Alkynyl]] | | [[Alkyne]] || [[Alkyne|Alkynyl]] | ||
| Line 45: | Line 45: | ||
| alkynyl- || -yne | | alkynyl- || -yne | ||
| <chem>H-C#C-H</chem><br>[[Acetylene]]<br>''(Ethyne)'' | | <chem>H-C#C-H</chem><br>[[Acetylene]]<br>''(Ethyne)'' | ||
|- | |- | ||
| [[Benzene|Benzene derivative]] | | [[Benzene|Benzene derivative]] | ||
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| RC<sub>6</sub>H<sub>5</sub><br>RPh | | RC<sub>6</sub>H<sub>5</sub><br>RPh | ||
| [[File:Phenyl-group.svg|75px|Phenyl]] | | [[File:Phenyl-group.svg|75px|Phenyl]] | ||
| phenyl- || | | phenyl- || ‑benzene | ||
| [[File:Cumene-skeletal.svg|75px]]<br>[[Cumene]]<br>''(Isopropylbenzene)'' | | [[File:Cumene-skeletal.svg|75px]]<br>[[Cumene]]<br>''(Isopropylbenzene)'' | ||
|} | |} | ||
There are also a large number of branched or ring alkanes that have specific names, e.g., [[tert-butyl]], [[bornyl]], [[cyclohexyl]], etc. There are several functional groups that contain an alkene such as [[vinyl group]], [[allyl group]], or [[Acryl|acrylic group]]. Hydrocarbons may form charged structures: positively charged [[carbocation]]s or negative [[carbanion]]s. Carbocations are often named ''-um''. Examples are [[tropylium]] and [[triphenylmethyl]] cations and the [[cyclopentadienyl]] anion. | There are also a large number of branched or ring alkanes that have specific names, e.g., [[tert-butyl]], [[bornyl]], [[cyclohexyl]], etc. There are several functional groups that contain an alkene such as [[vinyl group]], [[allyl group]], or [[Acryl|acrylic group]]. Hydrocarbons may form charged structures: positively charged [[carbocation]]s or negative [[carbanion]]s. Carbocations are often named ''-um''. Examples are [[tropylium]] and [[triphenylmethyl]] cations and the [[cyclopentadienyl]] anion. | ||
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===Groups containing oxygen=== | ===Groups containing oxygen=== | ||
Compounds that contain C–O bonds each possess differing reactivity based upon the location and [[orbital hybridisation|hybridization]] of the C–O bond, owing to the electron-withdrawing effect of | Compounds that contain C–O bonds each possess differing reactivity based upon the location and [[orbital hybridisation|hybridization]] of the C–O bond, owing to the electron-withdrawing effect of sp²-hybridized oxygen (carbonyl groups) and the donating effects of sp³-hybridized oxygen (alcohol groups). | ||
{| class="wikitable" style="background: #ffffff; text-align: center;width:300px" | {| class="wikitable" style="background: #ffffff; text-align: center;width:300px" | ||
|- | |- | ||
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|- | |- | ||
| [[Alcohol (chemistry)|Alcohol]] | | [[Alcohol (chemistry)|Alcohol]] | ||
|| [[Hydroxy]] | || [[Hydroxyl|Hydroxy]] | ||
| ROH | | ROH | ||
| [[File:Hydroxy-group-bw.svg|60px|center|Hydroxyl]] | | [[File:Hydroxy-group-bw.svg|60px|center|Hydroxyl]] | ||
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| RCOX | | RCOX | ||
| [[File:Acyl-halide-skeletal2D.svg|75px|Acyl halide]] | | [[File:Acyl-halide-skeletal2D.svg|75px|Acyl halide]] | ||
| carbonofluoridoyl-<br>carbonochloridoyl-<br>carbonobromidoyl-<br>carbonoiodidoyl- || -oyl ''' | | carbonofluoridoyl-<br>carbonochloridoyl-<br>carbonobromidoyl-<br>carbonoiodidoyl- || -oyl '''halide''' | ||
| [[File:Acetyl-chloride.svg|75px|Acetyl chloride]]<br>[[Acetyl chloride]]<br>''(Ethanoyl chloride)'' | | [[File:Acetyl-chloride.svg|75px|Acetyl chloride]]<br>[[Acetyl chloride]]<br>''(Ethanoyl chloride)'' | ||
|- | |- | ||
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| alkanoyloxy-<br>or<br>alkoxycarbonyl | | alkanoyloxy-<br>or<br>alkoxycarbonyl | ||
| alkyl alkan'''oate''' | | alkyl alkan'''oate''' | ||
| [[File: | | [[File:Ethylbutyrat.svg|75px|Ethyl butyrate]]<br>[[Ethyl butyrate]]<br>''(Ethyl butanoate)'' | ||
|- | |- | ||
| [[Organic peroxide|Hydroperoxide]] | | [[Organic peroxide|Hydroperoxide]] | ||
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| [[Hemiketal]] || [[Hemiketal]] | | [[Hemiketal]] || [[Hemiketal]] | ||
| RC(ORʺ)(OH)R′ | | RC(ORʺ)(OH)R′ | ||
| [[File:Hemiketal-2D-skeletal. | | [[File:Hemiketal-2D-skeletal.svg|75px|Hemiketal]] | ||
| alkoxy -ol | | alkoxy -ol | ||
| -one alkyl '''hemiketal''' | | -one alkyl '''hemiketal''' | ||
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| [[File:1°-amino-group.png|75px|Primary amine]] | | [[File:1°-amino-group.png|75px|Primary amine]] | ||
| amino- || -amine | | amino- || -amine | ||
| [[File:Methylamine-2D. | | [[File:Methylamine-2D.svg|75px|methylamine]]<br>[[Methylamine]]<br>''(Methanamine)'' | ||
|- | |- | ||
| [[amine|Secondary amine]] | | [[amine|Secondary amine]] | ||
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|- | |- | ||
| [[imine|Secondary ketimine]] | | [[imine|Secondary ketimine]] | ||
| RC(=NR | | RC(=NR")R' | ||
| [[File:Imine-(secondary)-skeletal.svg|75px|Imine]] | | [[File:Imine-(secondary)-skeletal.svg|75px|Imine]] | ||
| imino- || -imine | | imino- || -imine | ||
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| cyano- | | cyano- | ||
| alkane'''nitrile'''<br>alkyl '''cyanide''' | | alkane'''nitrile'''<br>alkyl '''cyanide''' | ||
| [[File:Benzonitrile | | [[File:Benzonitrile.svg|75px|Benzonitrile]]<br>[[Benzonitrile]]<br>''(Phenyl cyanide)'' | ||
|- | |- | ||
| [[Isonitrile]] || RNC | | [[Isonitrile]] || RNC | ||
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| -thioyl-<br>(-CSR')<br>or<br>sulfanylidene-<br>(=S) | | -thioyl-<br>(-CSR')<br>or<br>sulfanylidene-<br>(=S) | ||
| -'''thione''' | | -'''thione''' | ||
| [[File:Thiobenzophenone | | [[File:Thiobenzophenone.svg|75px|Diphenylmethanethione]]<br>[[Diphenylmethanethione]]<br>([[Thiobenzophenone]]) | ||
|- | |- | ||
| [[Thial]] | | [[Thial]] | ||
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| methanethioyl-<br>(-CSH)<br>or<br>sulfanylidene-<br>(=S) | | methanethioyl-<br>(-CSH)<br>or<br>sulfanylidene-<br>(=S) | ||
| -'''thial''' | | -'''thial''' | ||
| | |[[File:Thioformaldehyde-2D.png|frameless|70x70px]] | ||
[[Thioformaldehyde]] | |||
(methanethial) | |||
|- | |- | ||
|rowspan=2| [[Thiocarboxylic acid]] | |rowspan=2| [[Thiocarboxylic acid]] | ||